SIGMA ALLIED CHEMICAL
St. Louis, HO 63103, US Technical Phone: 3147715765 Emergency Phone: 3147715765 Fax: 8003255052
SECTION 1. CHEMICAL IDENTIFICATION- CATALOG #: B86907
NAME: TERT.-BUTOXYCARBONYL AZIDE, 99%
SECTION 2. --COMPOSITION/INFORMATION ON INGREDIENTS CAS #: 1070-19-5
MF: C5H9N3O2
EC NO: 213-972-8
SECTION 3. HAZARDS IDENTIFICATION LABEL PRECAUTIONARY STATEMENTS
HARMFUL
RISK OF EXPLOSION BY SHOCK, FRICTION, FIRE OR OTHER SOURCES OF IGNITION.
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
KEEP AWAY FROM HEAT
AVOID SHOCK AND FRICTION.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELI. WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 4. FIRST-AID MEASURES- IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS CALL
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN CASE OF SKIN CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST lS MINUTES. REMOVE CONTAMINATED CLOTHING AND
SHOES. CALL A PHYSICIAN.
IN CASE OF CONTACT WITH E~ES, FLUSH WITH COPIOUS AMOUNTS OF WATER
FOR AT LEAST lS MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING
THE EYELIDS WITH FINGERS. CALL A PHYSICIAN.
SECTION 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA
CARBON DIOXIDE, DR~ CHEMICAL POWDER OR APPROPRIATE FOAM.
WATER SPRAY.
SPECIAL FIREFIGHTING PROCEDURES
WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS.
UNUSUAL FIRE AND EXPLOSIONS HAZARDS
MA~ EXPLODE WHEN HEATED.
MAY BE SHOCK-SENSITIVE.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
EXPLOSIVE.
SECTION 6. ACCIDENTAL RELEASE MEASURES- WEAR SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY
RUBBER GLOVES.
ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE EVACUATE AREA.
SECTION 7. HANDLING AND STORAGE- REFER TO SECTION 8.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION-
SAFETY SHOWER AND E~E BATH.
MECHANICAL EXHAUST REQUIRED.
AVOID PROLONGED OR REPEATED EX~OSURE.
DO NOT BREATHE VAPOR.
AVOID CONTACT WITH EYES, S~IN AND CLOTHING.
NIOSH!MSHA-APPROVED RESPIRATOR.
COMPATIBLE CHEMICAL-RESISTANT GLOVES.
CHEMICAL SAFETY GOGGLES.
WASH THOROUGHLY AFTER HANDLING.
STORE IN A COOL DRY PLACE.
REFRIGERATE.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL PROPERTIES
BOILING POINT: 73 C TO 76 C/70MM.
SPECIFIC GRAVITY: 1.034
SECTION 10. STABILITY AND REACTIVITY STABILITY
STABLE.
INCOMPATIBILITIES
MAY BE HEAT AND SHOCK SENSITIVE.
STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS
CARBON MONOXIDE, CARBON DIOXIDE
NITROGEN OXIDES
HAZARDOUS POLYMERIZATION
WILL NOT OCCUR.
SECTION 11. TOXICOLOGICAL INFORMATION ACUTE EFFECTS
MAY CAUSE SKIN IRRITATION.
HARMFUL IF ABSORBED THROUGH SKIN.
MAY CAUSE EYE IRRITATION.
HARMFUL IF INHALED.
MATERIAL MAY BE IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATOR~ TRACT.
HARMFUL IF SWALLOWED.
EXPOSURE CAN CAUSE:
NAUSEA, HEADACHE AND VOMITING
MANY AZIDES CAUSE A FALL IN BLOOD PRESSURE AND SOME INHIBIT ENZ~ME ACTION.
CHRONIC EFFECTS
TARGET ORGAN(S) :
BRAIN
HEART
NERVES
RTECS *: LQ5270000
SECTION 12. ECOLOGICAL INFORMATION DATA NOT YET AVAILABLE.
SECTION 13. DIS~OSAL CONSIDERATIONS CONTACT A LICENSED PROFESSIONAL WASTE DISPOSAL SERVICE TO DISPOSE OF
THIS MATERIAL.
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. SECTION 14. TRANSPORT INFORMATION CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION INFORMATION.
SECTION 15. REGULATORY INFORMATION EUROPEAN INFORMATION
HARMFUL
R 2
RIS~ OF EXPLOSION B~ SHOCK, FRICTION, FIRE OR OTHER SOURCES OF IGNITION.
R 20/21/22
HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED.
S lS
KEEP AWAY FROM HEAT
S 35
AVOID SHOCK AND FRICTION.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 16. OTHER INFORMATION- THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE ~RODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
COPYRIGHT 1999 SIGMA-ALDRICH CO. KEEP AWAY FROM HEAT
S 35
AVOID SHOCK AND FRICTION.
S 26
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF
WATER AND SEEK MEDICAL ADVICE.
S 36
WEAR SUITABLE PROTECTIVE CLOTHING.
SECTION 16. OTHER INFORMATION- THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA, ALDRICH,
FLUKA SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING
OR FROM CONTACT WITH THE ABOVE ~RODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE. KEEP AWAY FROM HEAT