(w/ Versa Clark and Ryan McGorty, UMass physics; Michael Nikolaides
and Andreas Bausch, T. U. Munich; Cyprien Gay, CRPP-CNRS, France; Ming Hsu, Michael Brenner and David Weitz,
Harvard)
Electrostatic and capillary forces at liquid
interfaces
Colloidal particles adsorbed at an
oil-water interface exhibit a surprising long-range attraction in
addition to the expected electrostatic repulsion. We propose
that the charges on the colloidal particles create electric fields
that induce polarization charges at the interface (owing to the
different dielectric constants of the two fluids). The field pushes
on the polarization charges and distorts the interface, which leads to
a long-range capillary attraction [article]. We can measure these forces directly using video microscopy and (sometimes) laser tweezers.